What is the most highly populated rotational level of Cl2 (i) 25deg C and (ii) 100 deg C? Take B=0.244cm-1.This question should not be resubmitted, it is a textbook question from the Atkins physical chemistry txtbook. 10 e.

Answers

Answer 1

Answer:

i

[tex]J_{m} = 20 [/tex]

ii

[tex]J_{m} = 22.5 [/tex]

Explanation:

From the question we are told that

  The first temperatures is [tex]T_1 =  25^oC =  25 +273 =298 \ K[/tex]

   The second temperature is  [tex]T_2 =  100^oC =  100 +273 = 373 \ K[/tex]

Generally the equation for  the most highly populated rotational energy level is mathematically represented as

     [tex]J_{m} = [ \frac{RT}{2B}]  ^{\frac{1}{2} } - \frac{1}{2}[/tex]

Here R is the gas constant with value [tex]R =8.314 \ J\cdot K^{-1} \cdot mol^{-1}[/tex]

Also  

      B is given as [tex]B=\ 0.244 \ cm^{-1}[/tex]

   Generally the energy require per mole to move 1 cm is  12 J /mole

So   [tex]0.244 \ cm^{-1}[/tex]  will require x J/mole

           [tex]x =  0.244 *  12[/tex]

=>          [tex]x =  2.928 \ J/mol [/tex]

So at the first temperature

     [tex]J_{m} = [ \frac{8.314 * 298  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 20 [/tex]

So at the second temperature

           [tex]J_{m} = [ \frac{8.314 * 373  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 22.5 [/tex]


Related Questions


1. What 2 subatomic particles have charges? List the particle name and its charge.

Answers

Answer: Proton - positive charge (+)

Neutron - neutral charge (0)

Electron - negative charge (-)

Explanation:

2 2 6 2 6 2 10 3
1s 2s 2p 3s 3p 4s 3d 4p
=

Answers

Answer:

ARSENIC

Explanation:

It has an atomic number of 33

Which is one way that minerals crystallize from materials dissolved in water?

from the air
from solutions that evaporate
from hot water solutions when water boils
from the soil

Answers

Answer:

the second answer its science behind it

Answer:

b

Explanation:

Carbonic acid, H2CO3, has two acidic hydrogens. A solution containing an unknown concentration of carbonic acid is titrated with potassium hydroxide. It requires 22.9 mL of 1.430 M KOH solution to titrate both acidic protons in 54.2 mL of the carbonic acid solution.

Required:
a. Write a balanced net ionic equation for the neutralization reaction. Include physical states.
b. Calculate the molarity of the carbonic acid solution.

Answers

Answer:

a. H₂CO₃(aq) + KOH(aq) ⇄ K₂CO₃(aq) + H₂O(l)

b. 0.603 M

Explanation:

Step 1: Write the neutralization reaction

H₂CO₃(aq) + KOH(aq) ⇄ K₂CO₃(aq) + H₂O(l)

Step 2: Calculate the reacting moles of KOH

22.9 mL of 1.430 M KOH react.

0.0229 L × (1.430 mol/L) = 0.0327 mol

Step 3: Calculate the reacting moles of H₂CO₃

The molar ratio of H₂CO₃ to KOH is 1:1. The reacting moles of H₂CO₃ are 1/1 × 0.0327 mol = 0.0327 mol.

Step 4: Calculate the molarity of H₂CO₃

0.0327 moles of H₂CO₃ are in a volume of 54.2 mL. The molarity of H₂CO₃ is:

M = 0.0327 mol/0.0542 L = 0.603 M

The molar mass of gallium (Ga) is 69.72 g/mol.
Calculate the number of atoms in a 27.2 mg sample of Ga.
Write your answer in scientific notation using three significant figures.
atoms Ga

Answers

Answer:

2.35 x 10²⁰ atoms Ga

Explanation:

After converting from mg to g, use the molar mass as the unit converter to convert to moles. Then using Avogadro's number, 6.022 x 10²³ convert from moles to atoms of Ga.

[tex]27.2mgGa*\frac{1g}{1000mg} *\frac{1 mol Ga}{69.72gGa} *\frac{6.022*10^2^3 atoms Ga}{1 molGa} = 2.349 * 10^2^0 atoms Ga[/tex]

Then round to 3 significant figures = 2.35 x 10²⁰ atoms Ga.

The number of atoms in 27.2 mg sample of Ga is 2.35 × 10²⁰ atoms

Stoichiometry

From the question, we are to calculate the number of atoms in a 27.2 mg sample of Ga.

First, we will determine the number of moles of Ga present

Using the formula,

[tex]Number\ of\ moles = \frac{Mass}{Molar\ mass} [/tex]

Mass = 27.2 mg = 0.0272 g

Molar mass = 69.72 g/mol

Then,

[tex]Number\ of\ moles \ of\ Ga = \frac{0.0272}{69.72} [/tex]

[tex]Number\ of\ moles \ of\ Ga = [/tex] 0.000390132 moles

Now, for the number of atoms present

From the formula

Number of atoms = Number of moles × Avogadro's constant

Then,

Number of Ga atoms = 0.000390132 × 6.022×10²³

Number of Ga atoms = 2.35 × 10²⁰ atoms

Hence, the number of atoms in 27.2 mg sample of Ga is 2.35 × 10²⁰ atoms

Learn more on stoichiometry here: https://brainly.com/question/14464650

In the laboratory you dissolve 18.7 g of copper(II) bromide in a volumetric flask and add water to a total volume of 375mL.

Required:
a. What is the molarity of the solution?
b. What is the concentration of the copper(II) cation?
c. What is the concentration of the acetate anion?

Answers

Answer:

a) - 0.2 M

b) - 0.2 M

c)- 0

Explanation:

The chemical formula of copper (II) bromide is CuBr₂. Its molar mass (MM) is calculated as follows:

MM(CuBr₂)= MM(Cu) + (2 x MM(Br) = 63.5 g/mol + (2 x 80 g/mol)= 223.5 g/mol

a). Molarity = moles CuBr₂/1 L solution

moles CuBr₂ = mass/MM = 18.7 g x 1 mol/223.5 g = 0.084 mol

Volume in L = 375 mL x 1 L/1000 mL = 0.375 L

M = 0.084 mol/(0.375 L) = 0.223 M ≅ 0.2 M

b). When is added to water, CuBr₂ dissociates into ions as follows:

CuBr₂ ⇒ Cu²⁺ + 2 Br⁻

We have 1 mol Cu²⁺ (copper (II) cation) per mol of CuBr₂. Thus, the concentration of copper (II) cation is:

0.2 mol CuBr₂ x 1 mol Cu²⁺/mol CuBr₂ = 0.2 M

c). The concentration of acetate anion is 0. There is no acetate anion in the solution (the anion from CuBr₂ is bromide Br⁻).

A balloon contains 1.1 L of gas at a pressure of 0.80 atm. How will the volume
change if the pressure is increased to 2.0 atm?

Answers

Answer:

Final volume  = 0.44 L

Explanation:

Given data:

Initial volume of balloon = 1.1 L

Initial pressure = 0.80 atm

Final volume = ?

Final pressure = 2.0 atm

Solution:

The given problem will be solved through the Boly's law,

"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"

Mathematical expression:

P₁V₁ = P₂V₂

P₁ = Initial pressure

V₁ = initial volume

P₂ = final pressure

V₂ = final volume  

Now we will put the values in formula,

P₁V₁ = P₂V₂

0.80 atm × 1.1 L = 2.0 atm × V₂

V₂ = 0.88 atm. L/ 2.0 atm

V₂ = 0.44 L

Solid diarsenic trioxide reacts with fluorine gas (F2) to produce liquid arsenic pentafluoride and oxygen gas (O2). Write the Qc for this reaction.

Answers

Answer:

QC= [O2]^3/[F2]^10

Explanation:

A student measured the masses of four different-sized blocks. The student determined that each block had a mass of 50 grams.


(There is a small block, a little bit bigger block, a big block and the biggles block)


Which block has the least density?

Answers

Answer:..

Explanation:

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